Start by preheating your oven to 350°F. Line an 8X8 baking pan with parchment paper, going up and over the sides.
In a large bowl with an electric mixer, beat together 1 cup granulated sugar and the orange zest from 2 oranges until combined.
Add 1 cup all-purpose flour, ½ cup natural cocoa powder, 1 teaspoon baking soda, ½ teaspoon baking powder, and ½ teaspoon kosher salt.
In another bowl, beat together 1 large room temperature egg, 1 teaspoon vanilla extract, ¼ cup milk (whole or 2%, room temperature), ¼ cup vegetable oil, and ¼ cup room temperature sour cream.
Gradually add the wet ingredients to the dry ingredients, mixing until just combined.
Pour the hot coffee into the batter and beat until fully incorporated. Do not over mix.
Pour into the pan, spreading it out evenly. Position it on the center rack of the oven to ensure even baking, avoiding placement too close to the top or bottom. Bake for 27-30 minutes or until a toothpick comes out clean.
Make the ganache once the cake is cooled down.